• 文献标题:   Carbon Nanomaterial-Based Copolymer of Styrene-Divinylbenzene Resins: Efficient Interaction Through Graphene/CNTs Polymer Network
  • 文献类型:   Article
  • 作  者:   LI YA, YU FP, HE WJ, YANG WM
  • 作者关键词:   composite, nanostructured polymer, resin, structureproperty relation, thermal propertie
  • 出版物名称:   JOURNAL OF APPLIED POLYMER SCIENCE
  • ISSN:   0021-8995 EI 1097-4628
  • 通讯作者地址:   SINOPEC Shanghai Res Inst Petrochem Technol
  • 被引频次:   4
  • DOI:   10.1002/app.41234
  • 出版年:   2015

▎ 摘  要

Carbon nanotubes (CNTs) and graphene were separately incorporated into the cross-linked network of styrene-divinylbenzene composites via in situ suspension polymerization. The prepared copolymers were first chloromethylated and then aminated with trimethylamine to obtain ion exchange resins (IERs). The CNTs-based and graphene-based composites exhibited good dispersion throughout the polymer matrix with strong interaction within the network. Remarkable enhancement in antiswelling properties and thermal stabilities confirmed that graphene showed better compatibility and stronger interfacial adhesion than CNTs. The structural and thermal properties of the CNTs-based and graphene-based IERs were also significantly improved even at low loadings of 0.4 wt % compared with those when no CNTs and graphene were added. (C) 2014 Wiley Periodicals, Inc.