• 文献标题:   A novel and reusable magnetic nanocatalyst developed based on graphene oxide incorporated strontium nanoparticles for the facial synthesis of beta-enamino ketones under solvent-free conditions
  • 文献类型:   Article
  • 作  者:   MOUSAVI SR, SERESHTI H, NODEH HR, FOROUMADI A
  • 作者关键词:   graphene oxide, magnetic nanocatalyst, solventfree, strontium, betaenamino ketone
  • 出版物名称:   APPLIED ORGANOMETALLIC CHEMISTRY
  • ISSN:   0268-2605 EI 1099-0739
  • 通讯作者地址:   Univ Tehran Med Sci
  • 被引频次:   3
  • DOI:   10.1002/aoc.4644
  • 出版年:   2019

▎ 摘  要

A novel magnetic SrFeGO nanocatalyst (NC) was synthesized through a simple sol-gel technique by introducing strontium and iron oxide nanoparticles onto graphene. The synthesized NC was characterized using FT-IR and FE-SEM. Subsequently, the catalytic activity of SrFeGO was tested in a reaction between beta-dicarbonyl compounds and aniline derivatives to gain beta-enamino ketone derivatives under solvent-free conditions. It was found that SrFeGO NC is a potential catalyst for the synthesis of beta-enamino ketones. The beta-enamino ketone produced by such reactions could be isolated in high purity without the need for chromatographic purifications. The newly prepared magnetic graphene oxide nanocomposite could be recovered and reused for numerous times with no significant decrease in efficiency. Moreover, the protocol has the advantages of excellent yielding (up to 98%) in short a reaction time, benefitting an easy workup procedure and being environmentally friendly.