• 文献标题:   Predicting experimentally stable allotropes: Instability of penta-graphene
  • 文献类型:   Article
  • 作  者:   EWELS CP, ROCQUEFELTE X, KROTO HW, RAYSON MJ, BRIDDON PR, HEGGIE MI
  • 作者关键词:   nanocarbon, modeling, allotrope, pentagraphene, haeckelite
  • 出版物名称:   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA
  • ISSN:   0027-8424
  • 通讯作者地址:   Univ Nantes
  • 被引频次:   32
  • DOI:   10.1073/pnas.1520402112
  • 出版年:   2015

▎ 摘  要

In recent years, a plethora of theoretical carbon allotropes have been proposed, none of which has been experimentally isolated. We discuss here criteria that should be met for a new phase to be potentially experimentally viable. We take as examples Haeckelites, 2D networks of sp(2)-carbon-containing pentagons and heptagons, and "penta-graphene," consisting of a layer of pentagons constructed from a mixture of sp(2)- and sp(3)-coordinated carbon atoms. In 2D projection appearing as the "Cairo pattern," penta-graphene is elegant and aesthetically pleasing. However, we dispute the author's claims of its potential stability and experimental relevance.