• 文献标题:   Graphene@attapulgite nanohybrid silicone Sol-gel coating toward good corrosion resistance
  • 文献类型:   Article
  • 作  者:   WANG JC, YAN H, TIAN S, PU JB, LU GM, REN LC, LIU ZX, FAN XQ, WANG LP
  • 作者关键词:   graphene, attapulgite, solgel, corrosion resistance
  • 出版物名称:   SURFACE TOPOGRAPHYMETROLOGY PROPERTIES
  • ISSN:   2051-672X
  • 通讯作者地址:   Southwest Jiaotong Univ
  • 被引频次:   0
  • DOI:   10.1088/2051-672X/abc9a9
  • 出版年:   2020

▎ 摘  要

Graphene with shielding effect can improve the corrosion resistance of organic coatings, but its high electrical conductivity intensifies the corrosion of metal substrate due to micro-galvanic effect on the interface of coating and substrate. The regulation of graphene's conductivity can inhibit the corrosion-promotion effect. Hence, graphene supported attapulgite (GNS-ATP) nanosheets with lower conductivity were successfully prepared by using TEOS as coupling agent, then were introduced into Sol-gel coatings via using gamma methacryloxypropyltrimethoxysilane (MPS) and tetraethyl orthosilicate (TEOS) as precursors. The characterization on corrosion resistance of the hybrid coatings illustrates that a small amount of well-dispersed GNS-ATP nanosheets can significantly enhance the corrosion resistance, mainly depending on the structure and performance characteristics of GNS-ATP nanosheets. Such advantages on reducing porosity and conductivity of hybrid coatings offer a better corrosion resistance.