• 文献标题:   Electrochemical Study of the Herbicide Paraquat Based on a Graphene-Zinc Oxide Nanocomposite
  • 文献类型:   Article
  • 作  者:   LIU H, CHEN MQ, LIN Y, LIU YH
  • 作者关键词:   graphene oxide/zno nanorod, screenprinted electrode, graphene, electrochemical determination, paraquat
  • 出版物名称:   INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE
  • ISSN:   1452-3981
  • 通讯作者地址:   Second Peoples Hosp Hengshui
  • 被引频次:   3
  • DOI:   10.20964/2017.09.15
  • 出版年:   2017

▎ 摘  要

Detection of the herbicide paraquat (PQ) is of great significance in the field of agriculture. To detect PQ, this work proposed the fabrication of a new electrochemical sensor based on graphene oxide/ZnO nanorod (GR/ZnO)-modified graphite screen-printed electrodes (SPEs). SPEs were used since they are small, low-cost and versatile. The GR/ZnO-modified SPE was prepared by casting a nanocomposite of the GR/ZnO nanorods on the SPE surface. The two reduction DPV peaks of PQ were remarkably strengthened with GR/ZnO at -0.60 V and -1.00 V. The reduction peak currents of PQ on the GR/ZnO-modified SPE were linear under the optimal conditions (concentration range: 0.05-2 mu M), and the limit of detection (LOD) was 21 nM.