• 文献标题:   Characterization of radioactive cobalt on graphene oxide by macroscopic and spectroscopic techniques
  • 文献类型:   Article
  • 作  者:   JIN ZX, SHENG J, SUN YB
  • 作者关键词:   sorption, co60 ii, graphene oxide, interaction mechanism
  • 出版物名称:   JOURNAL OF RADIOANALYTICAL NUCLEAR CHEMISTRY
  • ISSN:   0236-5731 EI 1588-2780
  • 通讯作者地址:   Chinese Acad Sci
  • 被引频次:   25
  • DOI:   10.1007/s10967-013-2918-8
  • 出版年:   2014

▎ 摘  要

Graphene oxide (GO) was synthesized using the modified Hummers method and characterized by XRD and FTIR. The sorption of Co-60(II) on GO as a function of contact time, pH, polyacrylic acid, ionic strength, temperature and solution concentration was studied by batch technique. The sorption kinetics indicated that the sorption of Co-60(II) on GO could be simulated by the pseudo-second-order model very well. The maximum sorption capacities of GO for Co-60(II) calculated from Langmuir model at pH 6.40 and T = 300 K was similar to 62.0 mg/g. The thermodynamic parameters from the temperature-dependent sorption isotherms indicated that the Co-60(II) sorption on GO was an endothermic and spontaneous process. The interaction mechanism between GO and Co(II) were outer-sphere surface complexation or ion exchange at pH <7, whereas the inner-sphere surface complexation was observed at pH 7-9 in terms of the analysis of XPS spectra.