• 文献标题:   Radiation synthesis of polysilane-modified graphene oxide for improving thermal conductivity and mechanical properties of silicone rubber
  • 文献类型:   Article
  • 作  者:   DAI P, JIAO Y, MA HL, ZENG XM, LU YJ, WANG LC, BAO M, ZHAI ML
  • 作者关键词:   graphene oxide, silicone rubber, radiation preparation, thermal conductivity
  • 出版物名称:   JOURNAL OF APPLIED POLYMER SCIENCE
  • ISSN:   0021-8995 EI 1097-4628
  • 通讯作者地址:   Beijing Res Ctr Radiat Applicat
  • 被引频次:   5
  • DOI:   10.1002/app.47776
  • 出版年:   2019

▎ 摘  要

Functionalized graphene oxide (named GO-Si) was synthesized with graphene oxide and triethoxyvinylsilane (TEVS) using tetrahydrofuran solution by -ray irradiation. TEVS was successfully covered onto GO sheets, and the polysilane content on GO-Si was increased upon increasing the absorbed dose. The structures of GO-Si were verified by atomic force microscopy, Fourier transform infrared spectroscopy, and X-ray photoelectron spectroscopy. The resultant GO-Si was dispersed into ,-dihydroxypolydimethylsiloxane to prepare room temperature vulcanized silicone rubber composites (named SR/GO-Si) by solution casting. The dispersion of GO-Si was more uniform than that of GO. Compared to that of pure SR, the thermal conductivity of SR/GO-Si-1.95 composites was increased 1.5-fold, and its tensile strength and elongation at break increased 78.6 and 71.4%, respectively. It was expected that SR/GO-Si would have potential application as the thermal interface material. (c) 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 136, 47776.