• 文献标题:   One pot synthesis of a highly water-dispersible hybrid glucose carbides and reduced graphene oxide material with superior electrical capacitance
  • 文献类型:   Article
  • 作  者:   SUN J, TENG XY, YANG JX, BI H
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS SCIENCE
  • ISSN:   0022-2461 EI 1573-4803
  • 通讯作者地址:   Anhui Univ
  • 被引频次:   7
  • DOI:   10.1007/s10853-013-7640-y
  • 出版年:   2013

▎ 摘  要

In this paper, reduced graphene oxide with glucose carbides (RGO-GC) was synthesized in a simple one pot synthesis via a hydrothermal approach. Graphene oxide (GO) dispersion was dissolved together with glucose in water, and the mixture was heated to 180 A degrees C in an autoclave. After hydrothermal treatment, a thin GO-like glucose carbides (GC) film grows in situ on the RGO surface. Differing from RGO, the obtained RGO-GC not only has a much better dispersion in water, but also can be used as a support and a green reductant to fabricate Ag-decorated RGO-GC. Moreover, the maximum specific capacitance of the RGO-GC reaches as high as 247 F g(-1) at a charging/discharging current density of 0.1 A g(-1) in 1 M H2SO4 solution. After 1000 charging/discharging cycles, the specific capacitance still retains 95 % of its initial specific capacitance. The greatly improved electrochemical performance is attributed to the increased surface wettability, more effective ionic diffusion, and a higher conductivity arising from the hydrophilic GO-like GC grown on the RGO surfaces.