• 文献标题:   Significantly reduced thermal diffusivity of free-standing two-layer graphene in graphene foam
  • 文献类型:   Article
  • 作  者:   LIN H, XU S, WANG XW, MEI N
  • 作者关键词:  
  • 出版物名称:   NANOTECHNOLOGY
  • ISSN:   0957-4484 EI 1361-6528
  • 通讯作者地址:   Iowa State Univ
  • 被引频次:   27
  • DOI:   10.1088/0957-4484/24/41/415706
  • 出版年:   2013

▎ 摘  要

We report on a thermal diffusivity study of suspended graphene foam (GF) using the transient electro-thermal technique. Our Raman study confirms the GF is composed of two-layer graphene. By measuring GF of different lengths, we are able to exclude the radiation effect. Using Schuetz's model, the intrinsic thermal diffusivity of the free-standing two-layer graphene is determined with a high accuracy without using knowledge of the porosity of the GF. The intrinsic thermal diffusivity of the two-layer graphene is determined at 1.16-2: 22 x 10(-4) x s(-1). The corresponding intrinsic thermal conductivity is 182-349 W m(-1) K-1, about one order of magnitude lower than those reported for single-layer graphene. Extensive surface impurity defects, wrinkles and rough edges are observed under a scanning electron microscope for the studied GF. These structural defects induce substantial phonon scattering and explain the observed significant thermal conductivity reduction. Our thermal diffusivity characterization of GF provides an advanced way to look into the thermal transport capacity of free-standing graphene with high accuracy and ease of experimental implementation.