• 文献标题:   Experimental combined theoretical study on chemical interactions of graphene oxide with chitosan and its resistive-switching effect
  • 文献类型:   Article
  • 作  者:   TRAN KM, DO DP, VU HN, NGUYEN TT, PHAN BT, THI KHT, PHAM KN
  • 作者关键词:   resistive switching, chitosan, graphene oxide, density functional theory
  • 出版物名称:   MATERIALS SCIENCE ENGINEERING BADVANCED FUNCTIONAL SOLIDSTATE MATERIALS
  • ISSN:   0921-5107 EI 1873-4944
  • 通讯作者地址:   VNU HCM
  • 被引频次:   1
  • DOI:   10.1016/j.mseb.2020.114788
  • 出版年:   2020

▎ 摘  要

Recently, nanocomposite materials that consist of chitosan (CS) and graphene oxide (GO) have received immense attention in many fields of research, such as biomedicine, environmental studies, energy and electronics. In this paper, we study resistive memory devices in capacitor-like Ag/CS-GO/FTO structures, with the CS-GO nanocomposites acting as the memory layer. The devices showed a bipolar resistive-switching effect under an external electric field, with the endurance of 10(3) and ON/OFF ratio around 10(2). The calculated results confirmed by using density-function-theory (DFT) calculations show the stability of CS-GO nanocomposites through the presence of peptide and hydrogen bonds. Moreover, the calculated HOMO-LUMO gap (HLG) of GO is within the HLG of CS, so several unoccupied levels of GO can serve as electron traps in CS-GO nanocomposites. Based on these results above, a resistive-switching mechanism in Ag/CS-GO/FTO devices can be proposed because of the trap/de-trap process of injected electrons under external electric field.