• 文献标题:   Layered reduced graphene oxide with nanoscale interlayer gaps as a stable host for lithium metal anodes
  • 文献类型:   Article
  • 作  者:   LIN DC, LIU YY, LIANG Z, LEE HW, SUN J, WANG HT, YAN K, XIE J, CUI Y
  • 作者关键词:  
  • 出版物名称:   NATURE NANOTECHNOLOGY
  • ISSN:   1748-3387 EI 1748-3395
  • 通讯作者地址:   Stanford Univ
  • 被引频次:   576
  • DOI:   10.1038/NNANO.2016.32
  • 出版年:   2016

▎ 摘  要

Metallic lithium is a promising anode candidate for future high-energy-density lithium batteries. It is a light-weight material, and has the highest theoretical capacity (3,860 mAh g(-1)) and the lowest electrochemical potential of all candidates. There are, however, at least three major hurdles before lithium metal anodes can become a viable technology: uneven and dendritic lithium deposition, unstable solid electrolyte interphase and almost infinite relative dimension change during cycling. Previous research has tackled the first two issues, but the last is still mostly unsolved. Here we report a composite lithium metal anode that exhibits low dimension variation (similar to 20%) during cycling and good mechanical flexibility. The anode is composed of 7 wt% 'lithiophilic' layered reduced graphene oxide with nanoscale gaps that can host metallic lithium. The anode retains up to similar to 3,390 mAh g(-1) of capacity, exhibits low overpotential (similar to 80 mV at 3 mA cm(-2)) and a flat voltage profile in a carbonate electrolyte. A full-cell battery with a LiCoO2 cathode shows good rate capability and flat voltage profiles.