• 文献标题:   Effects of ultrasound on synthesis and performance of manganese-based/ graphene oxide oxygen reduction catalysts for aluminum-air batteries
  • 文献类型:   Article
  • 作  者:   LONG GG, LIU Y, CHEN M, MA HY, CUI ZJ, WU MQ, FEI LP, SONG YF, LIU ZW
  • 作者关键词:   aluminumair battery, cathode catalyst, ultrasound
  • 出版物名称:   JOURNAL OF POWER SOURCES
  • ISSN:   0378-7753 EI 1873-2755
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.1016/j.jpowsour.2023.233150 EA MAY 2023
  • 出版年:   2023

▎ 摘  要

In this research, manganese (Mn) based/graphene oxide (GO) composites, which are used as cathode catalysts for aluminum(Al)-air battery are successfully prepared via ultrasound method using KMnO4-MnSO4-GO system. The effects of ultrasonic amplitude on the synthesis and performance of catalysts are both investigated. The result reveals that changing the ultrasonic amplitude (10, 15 mu m and 20 mu m) is able to effectively affect the composition of catalysts, and which further influence their electrocatalytic and discharging performance. The catalyst obtained under an ultrasonic amplitude of 15 mu m is composed of gamma-manganese oxyhydroxide (gamma-MnO(OH)), alpha-manganese dioxide (alpha-MnO2) and GO, which has good electrocatalytic performance closing to a commercial 20% Platinum (Pt)/Carbon (C) catalyst. This research proposes a novel and efficient method by using ultrasound to prepare Mn based/GO catalysts with excellent electrocatalytic performance, which exhibit great potential in the field of metal-air battaries.