▎ 摘　　要

3D graphene-based frameworks with interpenetrating macroporous structures have attracted great interests recently since they can serve as robust matrix for accommodating guest nanoparticles for use in a wide range of applications. Here, an adsorption-hydrothermal strategy is adopted for the in-situ growth of Ni(OH)(2) nanoplates using three dimensional (3D) nitrogen-containing graphene hydrogel (NG) as the substrate. The NG/Ni(OH)(2) nanocomposite hydrogel thus obtained is explored as the monolithic freestanding supercapacitor electrode without adding any other binders or conductive additives. The 3D hierarchical structure of the NG/Ni(OH)(2) nanocomposite can not only provide a large accessible surface area, but also facilitate ion diffusion and charge transport for much improved supercapacitive performance. The gel with Ni(OH)(2) loading of similar to 40% achieves a high specific capacitance of 782 F g (1) at the current density of 0.2 A g (1), which equals to a specific capacitance of 1748 F g (1) based on the mass of Ni(OH)(2) alone. Excellent cycling stability of only 10% capacitance loss after 10000 cycles is also achieved due to the robust adhesion between the metal hydroxide and nitrogen containing graphene. Furthermore, high capacitance retention of similar to 80% can be achieved when the current density is increased 100 fold from 0.2 to 20 A g (1). (C) 2016 Elsevier Ltd. All rights reserved.