• 文献标题:   Effect of aniline on cadmium adsorption by sulfanilic acid-grafted magnetic graphene oxide sheets
  • 文献类型:   Article
  • 作  者:   HU XJ, LIU YG, ZENG GM, WANG H, HU X, CHEN AW, WANG YQ, GUO YM, LI TT, ZHOU L, LIU SH, ZENG XX
  • 作者关键词:   gobased composite, sulfo group, cadmium, aniline, mutual effect
  • 出版物名称:   JOURNAL OF COLLOID INTERFACE SCIENCE
  • ISSN:   0021-9797 EI 1095-7103
  • 通讯作者地址:   Hunan Univ
  • 被引频次:   29
  • DOI:   10.1016/j.jcis.2014.04.016
  • 出版年:   2014

▎ 摘  要

Cd(II) has posed severe health risks worldwide. To remove this contaminant from aqueous solution, the sulfanilic acid-grafted magnetic graphene oxide sheets (MGOs/SA) were prepared and characterized. The mutual effects of Cd(II) and aniline adsorption on MGOs/SA were studied. The effects of operating parameters such as pH, ionic strength, contact time and temperature on the Cd(II) enrichment, as well as the adsorption kinetics and isotherm were also investigated. The results demonstrated that MGOs/SA could effectively remove Cd(II) and aniline from the aqueous solution and the two adsorption processes were strongly dependent on solution pH. The Cd(II) adsorption was reduced by the presence of aniline at pH < 5.4 but was improved at pH > 5.4. The presence of Cd(II) diminished the adsorption capacity for aniline at pH < 7.8 but enhanced the aniline adsorption at pH > 7.8. The decontamination of Cd(II) by MGOs/SA was influenced by ionic strength. Besides, the adsorption process could be well described by pseudosecond-order kinetic model. The intraparticle diffusion study revealed that the intraparticle diffusion was not the only rate-limiting step for the adsorption process. Moreover, the experimental data of isotherm followed the Freundlich isotherm model. (C) 2014 Elsevier Inc. All rights reserved.