• 文献标题:   Simultaneous Suppression of Metal Corrosion and Electrolyte Decomposition by Graphene Oxide Protective Coating in Magnesium-Ion Batteries: Toward a 4-V-Wide Potential Window
  • 文献类型:   Article
  • 作  者:   PRABAKAR SJR, PARK C, IKHE AB, SOHN KS, PYO M
  • 作者关键词:   nonnoble metal, graphene oxide, electrophoresi, corrosion, magnesiumion batterie
  • 出版物名称:   ACS APPLIED MATERIALS INTERFACES
  • ISSN:   1944-8244
  • 通讯作者地址:   Sunchon Natl Univ
  • 被引频次:   5
  • DOI:   10.1021/acsami.7b16103
  • 出版年:   2017

▎ 摘  要

Despite remarkable developments in electrolyte systems over the past decades, magnesium-ion batteries still suffer from corrosion susceptibility and low anodic limits. Herein we describe how graphene oxide (GO), coated onto non-noble metals (Al, Cu, and stainless steel) via- electrophoretic deposition, can solve this problem. In all phenyl complex electrolytes, GO coating results in a significant suppression of corrosion and extends the anodic limits' (up to 4.0 V vs Mg/Mg2+) with no impact on reversible Mg plating/stripping reactions. The same effect of GO coating is also established in magnesium aluminum chloride complex electrolytes. This remarkable-improvement is associated with the electtostatic interaction between the ionic charges of electrolytes and the-surface-functional groups of GO: In addition, GO coating, does not aggravate the cathode performance of Mo6S8, which allows the use of non-noble metals as current collectors. We also discuss, the role of GO in. increasing anodic limits when it is hybridized with alpha-MnO2.