• 文献标题:   Polyimide/graphene composite foam sheets with ultrahigh thermostability for electromagnetic interference shielding
  • 文献类型:   Article
  • 作  者:   LI Y, PEI XL, SHEN B, ZHAI WT, ZHANG LH, ZHENG WG
  • 作者关键词:  
  • 出版物名称:   RSC ADVANCES
  • ISSN:   2046-2069
  • 通讯作者地址:   Chinese Acad Sci
  • 被引频次:   88
  • DOI:   10.1039/c4ra16421k
  • 出版年:   2015

▎ 摘  要

Herein Kapton-type aromatic polyimide (PI) composite foams with reduced graphene oxide (rGO) content ranging from 1 to 16 wt% have been fabricated via a three-step method: in situ polymerization, nonsolvent induced phase separation and thermal imidization, and used for electromagnetic interference shielding. The resultant PI/16 wt% rGO foam with low density of 0.28 g cm(-3) and thickness of 0.8 mm exhibited an effective EMI shielding effectiveness of 17-21 dB in X band (8-12 GHz). Additionally, the thermostability of the foams was also significantly enhanced, for the 5% weight loss temperature it was improved from 508 degrees C for the pure PI foam to 520 degrees C for the PI/1 wt% rGO foam, and consequently, to 581 degrees C for the PI/16 wt% rGO foam. Even with the high rGO content (16 wt%), the composite foam was fairly flexible. Tensile testing revealed that the PI/16 wt% rGO foam possessed a tensile strength of 11.4 MPa and an elongation at break of 9.6%, respectively.