• 文献标题:   Synthesis and evaluation of carbon-coated Fe2O3 loaded on graphene nanosheets as an anode material for high performance lithium ion batteries
  • 文献类型:   Article
  • 作  者:   WANG G, WANG H, CAI SB, BAI JT, REN ZY, BAI JB
  • 作者关键词:   iron oxide, carbon coated, graphene nanosheet support, electrochemical performance, lithium ion batterie
  • 出版物名称:   JOURNAL OF POWER SOURCES
  • ISSN:   0378-7753
  • 通讯作者地址:   NW Univ Xian
  • 被引频次:   39
  • DOI:   10.1016/j.jpowsour.2013.03.105
  • 出版年:   2013

▎ 摘  要

A hybrid material of carbon-coated Fe2O3 submicro-particles loaded on graphene nanosheets (Fe2O3@C/GN5) is prepared by a two step route including a hydrothermal and a subsequent glucose impregnation-pyrolysis process. The obtained material is composed of GNs and similar to 400 nm size Fe2O3 particles coated by thin carbon layer with a thickness of 5 nm. As an anode material for lithium ion batteries, Fe2O3@C/GN5 hybrid shows an improved electrochemical performance in the initial coulombic efficiency (71%), reversible capacity (900 mA h g(-1) after 50 cycles at a current of 200 mA g(-1)) and capacity retention rate (82% after 50 cycles). This result is much better than the synthesized bare Fe2O3 and Fe2O3/GN5 electrodes. In addition to the contribution of GNs, the carbon-coated layer around Fe2O3 particles is believed to be a key factor to improve the electrochemical performance of Fe2O3. (C) 2013 Elsevier B.V. All rights reserved.