• 文献标题:   The effect of graphene-based nanofillers on the structure, thermal, and mechanical properties of poly(vinyl alcohol)
  • 文献类型:   Article
  • 作  者:   RAHBARSHENDI F, BAYBORDIANI A, ASGHARZADEH H, BADR M, HASSANNEZHAD K
  • 作者关键词:   coating, composite, graphene fullerene, mechanical propertie, thermal propertie
  • 出版物名称:   JOURNAL OF APPLIED POLYMER SCIENCE
  • ISSN:   0021-8995 EI 1097-4628
  • 通讯作者地址:  
  • 被引频次:   3
  • DOI:   10.1002/app.52664 EA MAY 2022
  • 出版年:   2022

▎ 摘  要

PVA matrix composite films reinforced with graphene oxide (GO) and reduced graphene oxide (rGO) nanoplatelets are prepared by water-solution processing. The structure and properties of the composites are investigated by field-emission scanning electron microscopy, Raman spectroscopy, Fourier-transform infrared spectroscopy, differential scanning calorimetry, and dynamic mechanical analysis. The results indicate a 22% improvement in the storage modulus and a 12 degrees C increase in the glass transition temperature by the addition of only 0.5 wt% rGO into the PVA. The enhancement of the mechanical and thermal properties of the composite films is attributed to the hydrogen bond barrier and molecule movement restriction effects. The higher amount of the hydrogen bonds in the PVA/rGO composite compared to the PVA/GO sample cause its higher thermal stability and mechanical performance.