• 文献标题:   Surface-amorphized TiO2 nanoparticles anchored on graphene as anode materials for lithium-ion batteries
  • 文献类型:   Article
  • 作  者:   LI C, ZHAO M, SUN CN, JIN B, YANG CC, JIANG Q
  • 作者关键词:   surface amorphous structure, tio2 nanoparticle, graphene, hybrid material, lithiumion batterie
  • 出版物名称:   JOURNAL OF POWER SOURCES
  • ISSN:   0378-7753 EI 1873-2755
  • 通讯作者地址:   Jilin Univ
  • 被引频次:   8
  • DOI:   10.1016/j.jpowsour.2018.07.019
  • 出版年:   2018

▎ 摘  要

One demanding challenge in the development of high-power batteries is to achieve superior rate and cycling performances. Here, we report a two-step method to fabricate a hybrid material of surface-amorphized TiO2/reduced graphene oxide (SA- TiO2/RGO), which exhibits superior electrochemical properties as an anode material in lithium-ion batteries, high rate property of 135.6 mAh g(-1) at a current density of 10 Ag-1 and cycling stability of 98 mAh g(-1) after 2000 cycles at 5 Ag-1. These excellent performances originate from the unique three-dimensional integrated structure of SA-TiO2/RGO, which provides: (i) a conductive substrate of RGO; (ii) higher conductivity of SA-TiO2 relative to crystallized-TiO2; (iii) ultra-small SA-TiO2 nanoparticles; and (iv) excellent contact between SA-TiO2 and RGO through C-O-Ti bonds.