• 文献标题:   A disposable and low-cost laser-scribed graphene electrochemical sensor for simultaneous detection of hydroquinone, paracetamol and methylparaben
  • 文献类型:   Article
  • 作  者:   KAVAI MS, DE LIMA LF, DE ARAUJO WR
  • 作者关键词:   laser fabrication, electrochemical sensor, simultaneous detection, disposable device
  • 出版物名称:   MATERIALS LETTERS
  • ISSN:   0167-577X EI 1873-4979
  • 通讯作者地址:  
  • 被引频次:   5
  • DOI:   10.1016/j.matlet.2022.133211 EA OCT 2022
  • 出版年:   2023

▎ 摘  要

A novel and inexpensive laser-scribed graphene (LSG) sensor using polyetherimide (PEI) substrate was fabricated using CO2 laser. The material was characterized by scanning electron microscopy (SEM), Raman spectroscopy, and electrochemical techniques, demonstrating a high porous carbonaceous material, which resulted in an electroactive area with 2.4-fold enhancement compared to geometric area and a high heterogeneous electron transfer rate constant (k degrees) of 3.20 x 10-2 cm/s for ferricyanide redox probe. As a proof of applicability, the LSG-PEI sensor was applied for simultaneous detection of hydroquinone (HQ), paracetamol (PA), and methylparaben (MP) emerging pollutants (EP) in tap water and natural (lake) water samples, providing recoveries between 93.1 % and 118 % with limits of detection of 9.42 x 10-8, 3.23 x 10-7, and 2.95 x 10-7 mol/L for HQ, PA, and MP, respectively.