• 文献标题:   Ru-Dye Grafted CuS and Reduced Graphene Oxide (CuS/rGO) Composite: An Efficient and Photo Tunable Electrode for Dye Sensitized Solar Cells
  • 文献类型:   Article
  • 作  者:   SARAVANAN KK, SIVAKARTHIK P
  • 作者关键词:   cus, reduced graphene oxide, composite, photovoltaic cell, energy conversion
  • 出版物名称:   JOURNAL OF CLUSTER SCIENCE
  • ISSN:   1040-7278 EI 1572-8862
  • 通讯作者地址:   Univ Coll Engn
  • 被引频次:   0
  • DOI:   10.1007/s10876-019-01653-1
  • 出版年:   2020

▎ 摘  要

The CuS@reduced graphene oxide (CuS/RGO) hybrid nanocomposite was synthesized by facile hydrothermal method and used as a photoelectrode material in photovoltaic applications. In the hydrothermal route, RGO is formed by the reduction of GO with simultaneous formation of CuS/RGO nanocomposites. The CuS/RGO nanocomposites was investigated using powder XRD, TEM, HR-TEM, Raman, XPS, DRS UV-Vis spectroscopy, Photoluminescence (PL) measurements. XRD and TEM results suggest that CuS crystalline with individual spherical like homogeneous nanoparticles sizes in the range of 45-35 nm, which is distributed throughout the RGO sheets. We further construct the flexible photoelectrodes by using CuS and RGO and studied the photovoltaic performance. Photovoltaic parameters, such as short-circuit photocurrent density, open circuit voltage, fill factor and conversion efficiency were found to be 16 mA/cm(2), 0.71 V, 70.1% and 7.81% respectively, for CuS/RGO photoelectrode. The improved photo conversion efficiency of CuS/RGO is due to enhancing the electronic injection ability and reducing the photogenerated charge recombination. These photovoltaic results indicate a simple methodology for the low cost and effortless synthesis of an alternative CuS/RGO photoelectrode in high performance photovoltaic devices.