• 文献标题:   Reduced graphene oxide-titanate hybrids: Morphologic evolution by alkali-solvothermal treatment and applications in water purification
  • 文献类型:   Article
  • 作  者:   NGUYENPHAN TD, PHAM VH, KIM EJ, OH ES, HUR SH, CHUNG JS, LEE B, SHIN EW
  • 作者关键词:   titanate, graphene, hybrid, solvothermal treatment, morphology control, adsorption
  • 出版物名称:   APPLIED SURFACE SCIENCE
  • ISSN:   0169-4332
  • 通讯作者地址:   Univ Ulsan
  • 被引频次:   37
  • DOI:   10.1016/j.apsusc.2012.01.026
  • 出版年:   2012

▎ 摘  要

The reduced graphene oxide-titanate (RGO-Ti) hybrids were fabricated by incorporating spherical TiO2 nanoparticles with graphene oxide (GO) layers in aqueous NaOH solution following by the solvothermal treatment. The morphologic evolution of RGO-Ti hybrid by varying alkali-solvothermal temperatures has been first investigated. The titanate nanosheets peeled off, folded and scrolled into tubular structure; and eventually, cracked and destroyed to be ribbon-like shape. The chemical interaction and attachment of low-dimensional titanate onto RGO layers and the reverse order were elucidated by X-ray photoelectron spectra. The hybrids in sheet and tubular titanate structures possessed larger surface areas (>350 m(2)/g) and higher pore volumes (>1 cm(3)/g) than the other. The presence of RGO sheets as a twodimensional (2D) platform for the deposition of titanate significantly promoted much better adsorptivity of dye contaminants compared to pure materials. (C) 2012 Elsevier B.V. All rights reserved.