• 文献标题:   In Situ DRIFTS Investigation of Ethylene Oxidation on Ag and Ag/Cu on Reduced Graphene Oxide
  • 文献类型:   Article
  • 作  者:   D OLIVEIRA MR, RABELO J, VEIGA AG, CHAGAS CA, SCHMAL M
  • 作者关键词:   reduced graphene oxide, epoxidation of ethylene, nanoparticle, silver, copper
  • 出版物名称:   CATALYSIS LETTERS
  • ISSN:   1011-372X EI 1572-879X
  • 通讯作者地址:   Univ Fed Rio de Janeiro
  • 被引频次:   1
  • DOI:   10.1007/s10562-020-03208-w EA APR 2020
  • 出版年:   2020

▎ 摘  要

Reduced graphene oxide (rGO) was synthesized and impregnated with silver and silver/copper for in situ DRIFTS investigation of ethylene oxidation. The catalysts were characterized using different techniques. SEM micrographs showed that the metals are dispersed on the rGO surface. XPS results showed the presence of the metallic silver and copper as CuO and Cu2O oxides. The in situ DRIFTS showed that in both catalysts the total oxidation of ethylene reaction prevails besides the intermediate formation of acetaldehyde. The presence of Cu ions or CuO and Cu2O at the surface indicate the presence of electronic structure, which may enhance the oxidation reaction. [GRAPHICS]