• 文献标题:   Fabrication of Graphene oxide membrane with multiple "Plug-ins" for efficient dye nanofiltration
  • 文献类型:   Article
  • 作  者:   PANG J, CUI XL, FENG Y, GUO ZJ, KONG GD, YU LT, ZHANG CY, WANG RM, KANG ZX, SUN DF
  • 作者关键词:   graphene oxide, betacyclodextrin, multiple plugins, nanofiltration
  • 出版物名称:   SEPARATION PURIFICATION TECHNOLOGY
  • ISSN:   1383-5866 EI 1873-3794
  • 通讯作者地址:  
  • 被引频次:   11
  • DOI:   10.1016/j.seppur.2021.119504 EA SEP 2021
  • 出版年:   2022

▎ 摘  要

The membranes based on graphene oxide (GO) have shown vast perspectives in nanofiltration, while the swelling of GO membranes in water environment poses a critical challenge for practical applications. In this study, we report the simple fabrication of stable GO membranes in water environment through intercalating multiple "plug-ins": the filter of beta-cyclodextrin (beta-CD) and the crosslinker of trimesoyl chloride (TMC), which can significantly enhance sieving effect and stability of membranes, and efficiently remove dyes and salts. The beta-CD possess the cavity range of 6.0-6.5 A which is larger than the diameter of water molecules, which can introduce extra water passage and hinder the permeation of dye molecules. In addition, the remaining hydroxyl groups on the membrane surface enhance the hydrophilicity, benefiting to enhance water permeance. At the same time, TMC cross-links beta-CD and GO nanosheets to reinforce the membrane. The water permeance of the GO/beta-CD/TMC membrane reaches 82 L m(-2)h(-1) bar(-1), and the dye rejection (crystal violet) is 99.98%. Therefore, GO membranes prepared by the multiple "plug-ins" incorporation strategy are promising candidates for the nanofiltration process to remove dyes.