• 文献标题:   Galvanic replacement synthesis of silver dendrites-reduced graphene oxide composites and their surface-enhanced Raman scattering characteristics
  • 文献类型:   Article
  • 作  者:   FU L, ZHU DM, YU AM
  • 作者关键词:   silver dendrite, reduced graphene oxide, composite, surfaceenhanced raman scattering, galvanic replacement
  • 出版物名称:   SPECTROCHIMICA ACTA PART AMOLECULAR BIOMOLECULAR SPECTROSCOPY
  • ISSN:   1386-1425
  • 通讯作者地址:   Swinburne Univ Technol
  • 被引频次:   30
  • DOI:   10.1016/j.saa.2015.04.049
  • 出版年:   2015

▎ 摘  要

A simple method was developed to synthesize Ag dendrites/reduced graphene oxide (AgD/RGO) composites based on the galvanic displacement method. AgNO3 was used as the precursor for Ag dendrites and aluminum foils served as the sacrifice metal. The as-synthesized AgD/RGO composite was characterized by SEM, FTIR, UV-vis spectroscopy and Raman spectroscopy. The results showed that the graphene oxide was successfully incorporated into the Ag dendritic structure and was reduced during the galvanic displacement between Ag+ ions and the aluminum foil. XRD analysis revealed that the Ag formed in the composite was in the cubic phase. The surface-enhanced Raman scattering (SERS) property of the as synthesized AgD/RGO composite was evaluated using Rhodamine B as a probe. The composite deposited substrate exhibited a much higher SERS activity compared with substrates modified with Ag dendrites or GO, indicating that the AgD/RGO could potentially be used as a highly sensitive SERS substrate for molecule detecting applications. (C) 2015 Elsevier B.V. All rights reserved.