• 文献标题:   Iron (III) Chloride doping of CVD graphene
  • 文献类型:   Article
  • 作  者:   SONG Y, FANG WJ, HSU AL, KONG J
  • 作者关键词:   graphene, chemical doping, transparent electrode, iron chloride
  • 出版物名称:   NANOTECHNOLOGY
  • ISSN:   0957-4484 EI 1361-6528
  • 通讯作者地址:   MIT
  • 被引频次:   18
  • DOI:   10.1088/0957-4484/25/39/395701
  • 出版年:   2014

▎ 摘  要

Chemical doping has been shown as an effective method of reducing the sheet resistance of graphene. We present the results of our investigations into doping large area chemical vapor deposition graphene using Iron (III) Chloride (FeCl3). It is shown that evaporating FeCl3 can increase the carrier concentration of monolayer graphene to greater than 10(14) cm(-2) and achieve resistances as low as 72 Omega sq(-1). We also evaluate other important properties of the doped graphene such as surface cleanliness, air stability, and solvent stability. Furthermore, we compare FeCl3 to three other common dopants: Gold (III) Chloride (AuCl3), Nitric Acid (HNO3), and TFSA ((CF3SO2)(2)NH). We show that compared to these dopants, FeCl3 can not only achieve better sheet resistance but also has other key advantages including better solvent stability.