• 文献标题:   Graphene based nanosensor for aqueous phase detection of nitroaromatics
  • 文献类型:   Article
  • 作  者:   AVAZ S, ROY RB, MOKKAPATI VRSS, BOZKURT A, PANDIT S, MIJAKOVIC I, MENCELOGLU YZ
  • 作者关键词:  
  • 出版物名称:   RSC ADVANCES
  • ISSN:   2046-2069
  • 通讯作者地址:   Sabanci Univ
  • 被引频次:   5
  • DOI:   10.1039/c7ra03860g
  • 出版年:   2017

▎ 摘  要

A graphene-based nanosensor was fabricated to selectively detect nitrotriazolone (NTO) molecules with a molecularly imprinted film via simple electrical measurements. Molecularly imprinted polymer comprising chitosan was used as sensitive layer. Gold electrodes for electrical measurements were lithographically fabricated on Si/SiO2 substrate, followed by monolayer graphene transfer and polymeric film coating. Monolayer graphene and molecularly imprinted polymer were characterized by ATR-FTIR, UV-Vis, SEM and Raman spectroscopy. Transfer-length measurements (TLM) indicate that the sensor selectively and linearly responds against aqueous NTO solutions within a wide range of concentration of 0.01-0.1 mg mL(-1) that covers the lowest toxic level of NTO determined by USEPA. This nanosensor with embedded electrodes is re-usable and suitable for field applications, offering real-time electrical measurements unlike current techniques where complex analytics are required.