• 文献标题:   Preparation and electrochemical analysis of graphene/polyaniline composites prepared by aniline polymerization
  • 文献类型:   Article, Proceedings Paper
  • 作  者:   KIM J, KIM S
  • 作者关键词:   polyaniline, graphene nanosheet, composite, electrochemical analysi, polymerization
  • 出版物名称:   RESEARCH ON CHEMICAL INTERMEDIATES
  • ISSN:   0922-6168 EI 1568-5675
  • 通讯作者地址:   Pusan Natl Univ
  • 被引频次:   7
  • DOI:   10.1007/s11164-014-1663-0
  • 出版年:   2014

▎ 摘  要

Polyaniline (PANI)/graphene nanosheet (GNS) composites were prepared by a chemical oxidation polymerization. The morphology, structure, and crystallinity of the composites were examined by scanning electron microscopy, transition electron microscopy, and X-ray diffraction. Electrochemical properties were characterized by cyclic voltammetry in 1 M H2SO4 electrolyte. GNS are considered as supporting materials which can provide a large number of active sites. The PANI nanofibers with diameter of 50 nm were homogeneously coated on the surface of GNS. The PANI/GNS composites exhibited a better electrochemical performance than the pure individual components. The PANI/GNS composites showed the highest specific capacitance 923 Fg(-1) at 10 mVs(-1) compared to 465 Fg(-1) for pure PANI and 99 Fg(-1) for GNS.