• 文献标题:   Monodisperse Chemically Modified Graphene Obtained by Density Gradient Ultracentrifugal Rate Separation
  • 文献类型:   Article
  • 作  者:   SUN XM, LUO DC, LIU JF, EVANS DG
  • 作者关键词:   graphene, density gradient, separation, ultracentrifuge, monodisperse
  • 出版物名称:   ACS NANO
  • ISSN:   1936-0851 EI 1936-086X
  • 通讯作者地址:   Beijing Univ Chem Technol
  • 被引频次:   141
  • DOI:   10.1021/nn1000386
  • 出版年:   2010

▎ 摘  要

A simple density gradient ultracentrifuge separation method has been developed for sorting chemically modified graphene (CMG) by sheet size and surface chemistry in just a few minutes. By optimizing the parameters, including the density gradient and centrifugation time, CMG sheets with specific size ranges and optical properties can be targeted selectively. UV vis absorbance and photoluminescence spectra revealed the properties of separated CMG samples are highly dependent on their sheet size and degree of oxidation. A possible mechanism for the separation is discussed.