• 文献标题:   Silver Nanoparticles Embedded on Reduced Graphene Oxide@Copper Oxide Nanocomposite for High Performance Supercapacitor Applications
  • 文献类型:   Article
  • 作  者:   ANSARI AR, ANSARI SA, PARVEEN N, ANSARI MO, OSMAN Z
  • 作者关键词:   reduced graphene oxide, metal, metal oxide, electrochemical device
  • 出版物名称:   MATERIALS
  • ISSN:  
  • 通讯作者地址:  
  • 被引频次:   10
  • DOI:   10.3390/ma14175032
  • 出版年:   2021

▎ 摘  要

In this work, silver (Ag) decorated reduced graphene oxide (rGO) coated with ultrafine CuO nanosheets (Ag-rGO@CuO) was prepared by the combination of a microwave-assisted hydrothermal route and a chemical methodology. The prepared Ag-rGO@CuO was characterized for its morphological features by field emission scanning electron microscopy and transmission electron microscopy while the structural characterization was performed by X-ray diffraction and Raman spectroscopy. Energy-dispersive X-ray analysis was undertaken to confirm the elemental composition. The electrochemical performance of prepared samples was studied by cyclic voltammetry and galvanostatic charge-discharge in a 2M KOH electrolyte solution. The CuO nanosheets provided excellent electrical conductivity and the rGO sheets provided a large surface area with good mesoporosity that increases electron and ion mobility during the redox process. Furthermore, the highly conductive Ag nanoparticles upon the rGO@CuO surface further enhanced electrochemical performance by providing extra channels for charge conduction. The ternary Ag-rGO@CuO nanocomposite shows a very high specific capacitance of 612.5 to 210 Fg(-1) compared against rGO@CuO which has a specific capacitance of 375 to 87.5 Fg(-1) and the CuO nanosheets with a specific capacitance of 113.75 to 87.5 Fg(-1) at current densities 0.5 and 7 Ag-1, respectively.