• 文献标题:   Nanohoneycomb-like manganese cobalt sulfide/three dimensional graphene-nickel foam hybid electrodes for high-rate capability supercapacitors
  • 文献类型:   Article
  • 作  者:   YU M, LI XJ, MA YX, LIU RL, LIU JH, LI SM
  • 作者关键词:   manganese cobalt sulfide, graphene, nanowall, supercapacitor
  • 出版物名称:   APPLIED SURFACE SCIENCE
  • ISSN:   0169-4332 EI 1873-5584
  • 通讯作者地址:   Beihang Univ
  • 被引频次:   29
  • DOI:   10.1016/j.apsusc.2016.11.203
  • 出版年:   2017

▎ 摘  要

Nanohoneycomb-like manganese cobalt sulfide/three dimensional graphene-nickel foam hybrid electrodes for supercapacitor are synthesized by chemical vapor deposition and electrodeposition. The ternary sulfide electrode exhibits high specific capacitance (1938 Fg(-1) at 5 A g(-1)) with excellent rate capability (76.8% capacitance retention at 100 A g(-1)) due to the intercrossed feature of the nanowalls and three-dimensional interpenetrating nanoarchitecture. Moreover, the specific capacitance of the electrode after 4000 cycles at a high current density of 50A g(-1) is 1320 Fg(-1). The asymmetric supercapacitor assembled with the manganese cobalt sulfide electrode and an activated carbon electrode displays an energy density of 14.33 W h kg(-1) at a power density of 74.87 W kg(-1). The manganese cobalt sulfide is a promising electrode material for practical application. (C) 2016 Elsevier B.V. All rights reserved.