• 文献标题:   In situ reduction of graphene oxide by different plant extracts as a green catalyst for selective hydrogenation of nitroarenes
  • 文献类型:   Article
  • 作  者:   KURT BZ, DURMUS Z, SEVGI E
  • 作者关键词:   green reduction, nitroarene, catalyst, graphene, palladium, hydrogenation
  • 出版物名称:   INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
  • ISSN:   0360-3199 EI 1879-3487
  • 通讯作者地址:   Bezmialem Vakif Univ
  • 被引频次:   2
  • DOI:   10.1016/j.ijhydene.2019.08.090
  • 出版年:   2019

▎ 摘  要

The reduction of graphene oxide (GO) was examined by using the extracts of different plants; cloves, white mulberry, black cumin seed, blackthorn, dark grape, and rosehip. The reduction efficiency of extracts was confirmed by XRD and spectroscopic analysis. The layered structure of reduced graphene and graphene nanocomposite decorated with palladium nanoparticles (PdNPs) was observed by electron microscopy techniques. This nanocomposite considered to be an active-selective catalyst for hydrogenation of nitroarenes in organic synthesis. This efficient catalyst can provide to develop clean, environmentally friendly, and energy-efficient production routes in industrial organic chemistry. It was concluded that the PdNPs/RGO catalyst showed high stability based on its reusing performance; seven times without loss of catalytic activity. (C) 2019 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.