• 文献标题:   Surface modification of graphene oxide with thermoresponsive polymers via atom transfer radical polymerization: Transition from LCST to UCST
  • 文献类型:   Article
  • 作  者:   YUAN WZ, WANG JJ, SHEN TX, REN J
  • 作者关键词:   graphene oxide, polymer, thermoresponsive, nanocomposite, surface
  • 出版物名称:   MATERIALS LETTERS
  • ISSN:   0167-577X EI 1873-4979
  • 通讯作者地址:   Tongji Univ
  • 被引频次:   11
  • DOI:   10.1016/j.matlet.2013.06.028
  • 出版年:   2013

▎ 摘  要

Graphene oxide-poly(2-N,N-dimethylamino)ethyl methacrylate (GO-PDMAEMA) nanocomposite was synthesized via atom transfer radical polymerization (ATRP) and PDMAEMA chains were grafted on the surface of GO. After quaternization, quaternized GO-PDMAEMA nanocomposite was achieved. GO-PDMAEMA shows a lower critical solution temperature (LCST)-type thermoresponsivity, and the dispersion-aggregation behavior was controlled by changing the temperature of the solution. The hydrophilicity of GO-PDMAEMA decreased with increasing temperature. Conversely, the dispersion and hydrophilicity of quaternized GO-PDMAEMA increased with increasing temperature due to the upper critical solution temperature (UCST)-type thermoresponsivity. So the LCST-UCST transition can be accomplished by the transition of PDMAEMA to quaternized PDMAEMA on the surface of GO. (C) 2013 Elsevier B.V. All rights reserved.