• 文献标题:   Poly(ethylene oxide)-promoted dispersion of graphene nanoplatelets and its effect on the properties of poly(lactic acid)/poly(butylene adipate-co-terephthalate) based nanocomposites
  • 文献类型:   Article
  • 作  者:   YE AL, WANG SJ, ZHAO Q, WANG YM, LIU CT, SHEN CY
  • 作者关键词:   poly lactic acid, poly butylene adipatecoterephthalate, graphene nanoplatelet, nanocomposite, polymeric composite
  • 出版物名称:   MATERIALS LETTERS
  • ISSN:   0167-577X EI 1873-4979
  • 通讯作者地址:   Zhengzhou Univ
  • 被引频次:   9
  • DOI:   10.1016/j.matlet.2019.06.040
  • 出版年:   2019

▎ 摘  要

Graphene nanoplatelets (GNP) is a relative new nanofiller used to tailor the morphology and properties of immiscible polymer blends. However, the self-agglomeration of GNP in the polymer matrix prevents the improvement in mechanical properties. In this work, a water-soluble polymer, poly(ethylene oxide) (PEO), was introduced to improve the dispersion of GNP in biodegradable immiscible poly(lactic acid) (PLA)/poly(butylene adipate-co-terephthalate) (PBAT) blends. PLA/PBAT based nanocomposites were prepared by melt-mixing PLA and PBAT with freeze-dried PEO/GNP masterbatch. It is found that a small amount of PEO incorporation (1 wt%) enhances the dispersion of GNP in the dispersed PBAT phase and reduces the complex viscosity of the systems significantly. Moreover, the presence of PEO enhances greatly the toughness and thermal stability of PLA/PBAT/GNP nanocomposites. The effect of the molecular weight of PEO was also addressed. (C) 2019 Elsevier B.V. All rights reserved.