▎ 摘　　要

The structural deformation during the embedding/de-embedding of K+ with a large ionic size is an important factor limiting the development of potassium-ion batteries (PIBs). The iron-based mixed polyanionic material Na4Fe3(PO4)(2)(P2O7) (NFPP) makes an excellent cathode material for PIBs due to its low cost, non-toxicity, suitable theoretical capacity, and stable structure. Here, a 3D reduced graphene oxide network wrapped NFPP (NFPP@rGO) was synthesized using a freeze-drying and subsequent annealing treatment. The NFPP@rGO material as a PIB cathode achieves a high discharge specific capacity of 119.1 mA h g(-1) at 0.1C and 80.3 mA h g(-1) even at 2C current density, and retains 82.1% of its initial capacity after 500 cycles. Ex situ XPS and XRD are utilized to understand the K+ storage mechanism of NFPP@rGO in PIBs. The superior electrochemical properties are due to the 3D reduced graphene oxide network, which improves the material's electrical conductivity and K+ diffusion rate, and stabilizes structural deformation during charge and discharge. These results indicate the feasibility of the NFPP@rGO cathode material for PIBs.