• 文献标题:   Copper(I) complex covalently anchored on graphene oxide as an efficient and recyclable catalyst for Sonogashira reaction
  • 文献类型:   Article
  • 作  者:   FATH RH, HOSEINI SJ
  • 作者关键词:   catalyst, graphene oxide, nanohybrid, organosilane, sonogashira reaction
  • 出版物名称:   APPLIED ORGANOMETALLIC CHEMISTRY
  • ISSN:   0268-2605 EI 1099-0739
  • 通讯作者地址:   Univ Yasuj
  • 被引频次:   3
  • DOI:   10.1002/aoc.3964
  • 出版年:   2018

▎ 摘  要

In this study, the organosilane-functionalized graphene oxide as a stabilizer was prepared by a facile one-step silylation approach. [Cu(PPh3)(3)Cl] complex was successfully immobilized onto the graphene oxide surface through coordination interaction with organosilane ligand spacers. The supported catalyst showed enhanced catalytic performance toward Sonogashira reaction of aryl halides with phenylacetylene in water solvent compared with the homogeneous analogues, and it could be readily recycled and reused several times without discernible loss of its activity.