• 文献标题:   Preparation of hydrophobic epoxy-polydimethylsiloxane-graphene oxide nanocomposite coatings for antifouling application
  • 文献类型:   Article
  • 作  者:   VERMA S, MOHANTY S, NAYAK SK
  • 作者关键词:  
  • 出版物名称:   SOFT MATTER
  • ISSN:   1744-683X EI 1744-6848
  • 通讯作者地址:   Cent Inst Plast Engn Technol CIPET
  • 被引频次:   5
  • DOI:   10.1039/c9sm01952a
  • 出版年:   2020

▎ 摘  要

Epoxy-polydimethylsiloxane-graphene oxide (EPG) nanocomposite coatings were successfully developed by loading different wt% of graphene oxide nanosheets (GNs) into an epoxy-hydroxy-terminated-polydimethylsiloxane (EP-hPD) matrixviaa facilein situpreparation technique. The inclusion of GNs into EPN led to an increase in modulus of elasticity and tensile strength up to 1570.46 MPa and 31.54 MPa, respectively, in the case of 1 wt% loading of GNs in the EP-hPD matrix. Also, an increase in the water contact angle from 90.1 degrees to 115.2 degrees, 104.5 degrees and 101.7 degrees was discerned at 1, 3 and 5 wt% loadings of GNs respectively. Taber abrasion results demonstrated a decrease in abrasion loss by 33.3% at 1 wt% loading of GNs in comparison to the unreinforced coating. An improvement in the glass transition temperature (T-g) was observed from 63.5 degrees C for the neat sample to 77.6 degrees C, 76.3 degrees C and 71.6 degrees C for the 1, 3 and 5 wt% EPG nanocomposites, respectively. An inevitable enhancement in the properties of the nanocomposites was affirmed due to the synergistic effect of GNs dispersed within the EP-hPD blend matrix. The prominent findings of this work include a minimum corrosion rate of 0.73 x 10(-2)mm per year and upgradation in the antifouling performance of the nanocomposite coatings in comparison to the neat coating.