• 文献标题:   Enhanced Li- and Na-storage in Sb-Graphene nanocomposite anodes
  • 文献类型:   Article
  • 作  者:   YI Y, SHIM HW, SEO SD, DAR MA, KIM DW
  • 作者关键词:   composite, nanostructure, chemical synthesi, electrochemical measurement, energy storage
  • 出版物名称:   MATERIALS RESEARCH BULLETIN
  • ISSN:   0025-5408 EI 1873-4227
  • 通讯作者地址:   Korea Univ
  • 被引频次:   15
  • DOI:   10.1016/j.materresbull.2015.12.044
  • 出版年:   2016

▎ 摘  要

Antimony-graphene nanocomposite (Sb-GNP) was prepared from commercially available graphene nanoplatelets (GNPs) by a simple wet-chemical route at room temperature, and systematically investigated as an anode material for both lithium- and sodium-ion batteries (LIBs and NIBs). The microstructural features of Sb-GNP, and of pure Sb nanoparticles prepared without addition of GNPs, were characterized using X-ray diffraction, field-emission scanning electron microscopy, and high-resolution transmission electron microscopy. The successful formation of a nanocomposite structure was observed for Sb-GNP; the Sb nanoparticles are well dispersed and anchored on graphene nanoplatelets without significant aggregation of Sb nanoparticles, in contrast to the pure Sb nanoparticles. Furthermore, galvanostatic studies revealed that Sb-GNP displays better Li- and Na-storage performance than the pure Sb nanoparticles when utilized as an anode material. The enhanced electrochemical performance can be attributed to the effects of nanocomposite formation with GNPs. (C) 2015 Elsevier Ltd. All rights reserved.