• 文献标题:   Highly sulfonated polymer-grafted graphene oxide composite membranes for proton exchange membrane fuel cells
  • 文献类型:   Article
  • 作  者:   LEE H, HAN J, KIM K, KIM J, KIM E, SHIN H, LEE JC
  • 作者关键词:   sulfonated poly arylene ether sulfone, graphene oxide, composite membrane, proton exchange membrane, fuel cell
  • 出版物名称:   JOURNAL OF INDUSTRIAL ENGINEERING CHEMISTRY
  • ISSN:   1226-086X EI 1876-794X
  • 通讯作者地址:   Seoul Natl Univ
  • 被引频次:   18
  • DOI:   10.1016/j.jiec.2019.03.012
  • 出版年:   2019

▎ 摘  要

Sulfonated poly(arylene ether sulfone) (SPAES) composite membranes were prepared using graphene oxide (GO) and sulfonated poly(arylene thioether sulfone)-grafted graphene oxide (SATS-GO) as fillers for proton exchange membrane fuel cell (PEMFC) applications. When GO and SATS-GO were mixed with SPAES to form the composite membranes, dimensional stability, chemical stability, and mechanical strength were improved. The composite membranes containing SATS-GO especially showed higher proton conductivity than the pristine SPAES and the composite membrane containing GO because of highly sulfonated polymer (SATS) introduced on GO surface. Furthermore, the sulfonic acid groups in SATS-GO can increase the compatibility between the filler and matrix polymer. (C) 2019 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.