• 文献标题:   Graphene/inorganic nanocomposites: Evolving photocatalysts for solar energy conversion for environmental remediation
  • 文献类型:   Article
  • 作  者:   KHAN M, ASSAL ME, TAHIR MN, KHAN M, ASHRAF M, HATSHAN MR, KHAN M, VARALA R, BADAWI NM, ADIL SF
  • 作者关键词:   graphene, nanocomposite, photocatalyst, solar energy, environmental remediation
  • 出版物名称:   JOURNAL OF SAUDI CHEMICAL SOCIETY
  • ISSN:   1319-6103 EI 2212-4640
  • 通讯作者地址:  
  • 被引频次:   7
  • DOI:   10.1016/j.jscs.2022.101544 EA OCT 2022
  • 出版年:   2022

▎ 摘  要

Current energy crisis and environmental issues, including depletion of fossil fuels, rapid industrialization, and undesired CO2 emission resulting in global warming has created havoc for the global population and significantly affected the quality of life. In this scenario the environmental problems in the forefront of research priorities. Development of renewable energy resources partic-ularly the efficient conversion of solar light to sustainable energy is crucial in addressing environ-mental problems. In this regard, the synthesis of semiconductors-based photocatalysts has emerged as an effective tool for different photocatalytic applications and environmental remedia-tion. Among different photocatalyst options available, graphene and graphene derivatives such as, graphene oxide (GO), highly reduced graphene oxide (HRG), and doped graphene (N, S, P, B-HRG) have become rising stars on the horizon of semiconductors-based photocatalytic applica-tions. Graphene is a single layer of graphite consisting of a unique planar structure, high conduc-tivity, greater electron mobility, and significantly very high specific surface area. Besides, the recent advancements in synthetic approaches have led to the cost-effective production of graphene-based materials on a large-scale. Therefore, graphene-based materials have gained considerable recogni-tion for the production of semiconducting photocatalysts involving other semiconducting materials. The graphene-based semiconductors photocatalysts surpasses electron-holes pairs recombination rate and lowers the energy band gap by tailoring the valence band (VB) and conduction band (CB) leading to the enhanced photocatalytic performance of hybrid photocatalysts. Herein, we have sum-marized the latest developments in designing and fabrication of graphene-based semiconducting photocatalysts using a variety of commonly applied methods such as, post-deposition methods, in-situ binding methods, hydrothermal and/or solvothermal approaches. In addition, we will discuss the photocatalytic properties of the resulting graphene-based hybrid materials for various environ-mental remediation processes such as; (i) clean H2 fuel production, photocatalytic (ii) pollutants degradation, (iii) photo-redox organic transformation and (iv) photo-induced CO2 reduction. On the whole, by the inclusion of more than 300 references, this review possibly covered in detail the aspects of graphene-based semiconductor photocatalysts for environmental remediation processes. Finally, the review will conclude a short summary and discussion about future perspectives, chal-lenges and new directions in these emerging areas of research.(c) 2022 The Authors. Published by Elsevier B.V. on behalf of King Saud University. This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/).