• 文献标题:   Doping of bi-layer graphene by gradually polarizing a ferroelectric polymer
  • 文献类型:   Article
  • 作  者:   KALBAC M, KONG J, DRESSELHAUS MS
  • 作者关键词:   doping, graphene, raman spectroscopy
  • 出版物名称:   PHYSICA STATUS SOLIDI BBASIC SOLID STATE PHYSICS
  • ISSN:   0370-1972 EI 1521-3951
  • 通讯作者地址:   ASCR
  • 被引频次:   2
  • DOI:   10.1002/pssb.201300053
  • 出版年:   2013

▎ 摘  要

The influence of the gradual polarization of a ferroelectric polymer on isotopically labeled bi-layer graphene has been investigated by Raman spectroscopy. The Raman frequencies of the C-13 graphene modes are downshifted with respect to the Raman frequencies of C-12 graphene, which enabled us to study the individual layer components of bi-layer graphene. The polarization of the ferroelectric polymer has a similar influence on the electron and hole concentration at the C-13 graphene and the C-12 graphene layer despite the C-13 graphene layer being only in direct contact with the ferroelectric polymer. In the Raman experiment the doping of graphene was confirmed by a similar frequency shift of the G modes and similar changes in the intensities of the G modes during the electrochemical charging of the ferroelectric polymer. (C) 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim