▎ 摘　　要

Reactive membranes (RMs) have attracted worldwide attention for wastewater purification and treatment due to their unique characteristics. In this study, through manipulating the band gap of graphene oxide (GO), a photo-Fenton GO membrane with enlarged inner channels, great selectivity and permeability as well as excellent self-cleaning ability was prepared for the first time via vacuum filtration. Notably, increased permeability (similar to 130.0 L m(-2).h(-1) bar(-1)) and enhanced dye removal efficiency (>= 99%) of the GO membrane are observed in the syn-ergistic photo-Fenton/filtration system. Additionally, the GO membrane maintained high flux and superior rejection properties after 10 repetitions, indicating its desirable stability and anti-fouling capabilities in photo-Fenton/filtration systems. The GO membrane can also be used as a photocatalyst and shows great removal ef-ficiency for MB (90.1%) in the photo-Fenton system. Besides, the mechanism of the self-cleaning property of the GO membrane is explored and it is found that the highly reactive center dot OH and center dot O-2(-) species contribute to membrane anti-fouling behavior. Based on our results, the GO membrane has potential for use as a self-cleaning membrane for advanced wastewater purification.