• 文献标题:   Quantum Confinement in Aligned Zigzag "Pseudo-Ribbons" Embedded in Graphene on Ni(100)
  • 文献类型:   Article
  • 作  者:   SALA A, ZOU ZY, CARNEVALI V, PANIGHEL M, GENUZIO F, MENTES TO, LOCATELLI A, CEPEK C, PERESSI M, COMELLI G, AFRICH C
  • 作者关键词:   1d electronic state, graphene, nickel, quantum confinement
  • 出版物名称:   ADVANCED FUNCTIONAL MATERIALS
  • ISSN:   1616-301X EI 1616-3028
  • 通讯作者地址:  
  • 被引频次:   4
  • DOI:   10.1002/adfm.202105844 EA NOV 2021
  • 出版年:   2022

▎ 摘  要

Lateral quantum confinement is of great interest in tuning the electronic properties of graphene-based nanostructures, making them suitable for technological applications. In principle, these properties might be controlled through the edge topology: for example, zigzag nanoribbons are predicted to have spin-polarized edge states. The practical realization of these structures is of utmost importance in fully harnessing the electronic properties of graphene. Here, the formation of regular, 1.4 nm wide ribbon-like graphene structures with zigzag edges are reported, showing 1D electronic states. It is found that these "pseudo-ribbons" embedded in single-layer graphene supported on Ni(100) can spontaneously form upon carbon segregation underneath 1D graphene moire domains, extending hundreds of nanometers in length. On the basis of both microscopy/spectroscopy/diffraction experiments and theoretical simulations, it is shown that these structures, even though seamlessly incorporated in a matrix of strongly interacting graphene, exhibit electronic properties closely resembling those of zigzag nanoribbons.