• 文献标题:   Glycine-functionalized reduced graphene oxide for methylene blue removal
  • 文献类型:   Article
  • 作  者:   WANG CB, MA GY, ZHOU JW, ZHANG ML, MA XF, DUO FF, CHU LL, HUANG JX, SU XM
  • 作者关键词:   adsorption, graphene, methylene blue, modification
  • 出版物名称:   APPLIED ORGANOMETALLIC CHEMISTRY
  • ISSN:   0268-2605 EI 1099-0739
  • 通讯作者地址:   Xinxiang Univ
  • 被引频次:   0
  • DOI:   10.1002/aoc.5077 EA JUL 2019
  • 出版年:   2019

▎ 摘  要

Glycine-functionalized reduced graphene oxide (GRGO) was prepared through the reaction of glycine and chlorine-functionalized reduced graphene oxide. The product was characterized by SEM, HRTEM, IR, Raman, and XPS. The nitrogen content (8.28%) was high in product, peak at 285.8 eV was assigned to the C-N bond, which implied that the chlorine residues in raw material were substituted by amine group of glycine. The intensity ratio of D and G peak was about 1.5, which also implied that more saturated carbon atoms were present in the product. Results of SEM, IR, and XPS confirmed that glycine molecules were attached to graphene sheets. Compared with reduced graphene oxide (61.5 mg/g) and active carbon (45.2 mg/g), GRGO had a good adsorption capacity (98.9 mg/g) for methylene blue. The adsorption process was fitted to three kinetic models and three adsorption isotherm models. The adsorption process complied with pseudo-second order kinetic model and Langmuir model.