• 文献标题:   Simonkolleite-graphene foam composites and their superior electrochemical performance
  • 文献类型:   Article
  • 作  者:   MOMODU DY, BARZEGAR F, BELLO A, DANGBEGNON J, MASIKHWA T, MADITO J, MANYALA N
  • 作者关键词:   simonkolleite sheet, graphene foam, composite, supercapacitor
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:   Univ Pretoria
  • 被引频次:   27
  • DOI:   10.1016/j.electacta.2014.11.015
  • 出版年:   2015

▎ 摘  要

Simonkolleite-graphene foam (SimonK/GF) composite has been synthesized by a facile solvothermal and environmentally friendly technique with excellent electrochemical properties. The obtained product was initially analyzed by scanning electron microscopy (SEM), Brunauer-Emmett-Teller (BET), X-ray diffraction (XRD), Fourier transform infrared resonance (FTIR) spectroscopy and cyclic voltammetry (CV) techniques. The microscopy results reveal hexagonal sheets interlaced with each other and adjacent graphene sheets. The existence of graphene foam in the simonK/GF composite is further confirmed from the structural and the optical characteristics obtained from XRD and FTIR respectively. The BET results obtained indicate an improvement in the surface area due to the addition of graphene foam to a value of 39.58 m2 g(-1). The N-2 adsorption/desorption also shows the presence of active mesopores required for charge transport. As a promising electrode material for supercapacitors, the composite shows a high specific capacitance value of 1094 F/g at 1 A/g with a coulombic efficiency of 100% after 1000 cycles. These results show a potential for adoption of this composite in energy storage applications. Crown Copyright (C) 2014 Published by Elsevier Ltd. All rights reserved.