• 文献标题:   Synthesis of Multimetal-Graphene Composite by Mechanical Milling
  • 文献类型:   Article
  • 作  者:   SAIPHANEENDRA B, SRIVASTAVA AK, SRIVASTAVA C
  • 作者关键词:  
  • 出版物名称:   JOM
  • ISSN:   1047-4838 EI 1543-1851
  • 通讯作者地址:   Indian Inst Sci
  • 被引频次:   2
  • DOI:   10.1007/s11837-016-1970-6
  • 出版年:   2016

▎ 摘  要

Multimetal-graphene composites were synthesized using the ball milling technique. To prepare the composite, graphite powder was mixed with Fe, Cr, Co, Cu and Mg powders. This mixture was then mechanically milled for 35 h in toluene medium. After milling, the multimetal-graphite mixture was mixed with sodium lauryl sulfate and sonicated for 2 h. Sonication led to the exfoliation of graphene sheets. Formation of graphene was confirmed from x-ray diffraction and Raman spectroscopy. Transmission electron microscopy-based analysis revealed the formation of multimetal deposits over the graphene surface. Compositional analysis of the multimetal deposits revealed fairly uniform distribution of all the five component metal atoms over the graphene sheet. The average composition of the multimetal deposit was determined to be 11.4 +/- A 4 at.% Mg, 33.8 +/- A 19 at.% Cr, 21.8 +/- A 16 at.% Fe, 9.4 +/- A 5.7 at.% Co and 23.6 +/- A 12 at.% Cu.