• 文献标题:   Temperature and Copper Concentration Effects on the Formation of Graphene-Encapsulated Copper Nanoparticles from Kraft Lignin
  • 文献类型:   Article
  • 作  者:   LENG WQ, BARNES HM, CAI ZY, ZHANG JL
  • 作者关键词:   temperature, copper concentration, grapheneencapsulated copper nanoparticle
  • 出版物名称:   MATERIALS
  • ISSN:   1996-1944
  • 通讯作者地址:   Mississippi State Univ
  • 被引频次:   4
  • DOI:   10.3390/ma10060677
  • 出版年:   2017

▎ 摘  要

The effects of temperature and copper catalyst concentration on the formation of graphene-encapsulated copper nanoparticles (GECNs) were investigated by means of X-ray diffraction, Fourier transform infrared spectroscopy-attenuated total reflectance, and transmission electron microscopy. Results showed that higher amounts of copper atoms facilitated the growth of more graphene islands and formed smaller size GECNs. A copper catalyst facilitated the decomposition of lignin at the lowest temperature studied (600 degrees C). Increasing the temperature up to 1000 degrees C retarded the degradation process, while assisting the reconfiguration of the defective sites of the graphene layers, thus producing higher-quality GECNs.