• 文献标题:   Enhancing the photocatalytic activity of ZnO nanoparticles for efficient rhodamine B degradation by functionalised graphene nanoplatelets
  • 文献类型:   Article
  • 作  者:   WORAJITTIPHON P, PINGMUANG K, INCEESUNGVORN B, WETCHAKUN N, PHANICHPHANT S
  • 作者关键词:   nanocomposite, zno, carbon material, photocatalysi
  • 出版物名称:   CERAMICS INTERNATIONAL
  • ISSN:   0272-8842 EI 1873-3956
  • 通讯作者地址:   Chiang Mai Univ
  • 被引频次:   15
  • DOI:   10.1016/j.ceramint.2014.09.023
  • 出版年:   2015

▎ 摘  要

Amine-functionalised graphene nanoplatelets were decorated with ZnO nanoparticles using a hydrothermal method to improve the photocatalytic activity of the ZnO in dye degradation. Nanocomposite characterisations using X-ray diffraction, Raman spectroscopy and transmission electron microscopy reveal effective interactions between the two constituents. The nanocomposite structure contributes to a high specific surface area, which increases the number of active sites, thus improving the light harvesting ability and the electron transfer efficiency and, subsequently, increasing the photogenerated electron-hole pair separation rate, as shown by the UV-vis diffuse reflectance spectroscopy and photoluminescence results. The resultant enhancement in the photocatalytic activity under ultraviolet light is demonstrated via rhodamine B degradations of up to 98.16% within 40 min, an exceptional degradation rate of 0.138 min(-1). The nanocomposite could alternatively be a new class of photocatalyst materials with potential uses in the remediation of polluted water. (C) 2014 Elsevier Ltd and Techna Group S.r.l. All rights reserved.