• 文献标题:   Immobilization of Quantum Dots on Fluorescent Graphene Oxide for Ratiometric Fluorescence Detection of Copper Ions
  • 文献类型:   Article
  • 作  者:   ZHU HJ, XU HD, YU H, ZHANG K, HAYAT T, ALSAEDI A, WANG SH
  • 作者关键词:   fluorescent graphene oxide, quantum dot, copper ions detection, ratiometric fluorescence, visual detection
  • 出版物名称:   CHEMISTRYSELECT
  • ISSN:   2365-6549
  • 通讯作者地址:   North China Elect Power Univ
  • 被引频次:   6
  • DOI:   10.1002/slct.201700899
  • 出版年:   2017

▎ 摘  要

Graphene oxide with stable fluorescence has been synthesized and utilized to support and functionalize quantum dots for dual- emissive nanostructure construction. The two emissions from graphene oxide and quantum dots are differently and independently responsive to copper ions (Cu2+). The blue fluorescence of graphene oxide is very stable against Cu2+, whereas the red fluorescence from quantum dots can be selectively quenched, inducing the composite fluorescent color change from bright red to blue. Such a novel nanocomposite can be applied for selective and sensitive determination of Cu2+. For practical application, the graphene based nanohybrid has been immobilized in polymer film to fabricate fluorescence test strip for Cu2+. A visual detection limit of 0.1 mu M for the film test strip has been estimated and shows the potential application for on-site visual determination of Cu2+ with no need for elaborate equipment.