• 文献标题:   Cobalt phthalocyanine-graphene complex for electro-catalytic oxidation of dopamine
  • 文献类型:   Article
  • 作  者:   YANG JH, MU D, GAO YJ, TAN J, LU AH, MA D
  • 作者关键词:   cobalt phthalocyaninegraphene, dopamine, electrooxidation, selective detection
  • 出版物名称:   JOURNAL OF NATURAL GAS CHEMISTRY
  • ISSN:   1003-9953
  • 通讯作者地址:   Peking Univ
  • 被引频次:   28
  • DOI:   10.1016/S1003-9953(11)60363-0
  • 出版年:   2012

▎ 摘  要

Cobalt phthalocyanine-graphene (CoPc-Gr) complex are fabricated through pi-pi interaction of each components, with CoPc adsorbed/inserted on/in the graphene sheets. The obtained complex could be used in the electro-chemical detection of various medicines. CoPc-Gr modified glassy electrode shows excellent response to the electro-oxidation of dopamine (DA) and ascorbic acid (AA), much better than those of CoPc, graphene oxide (GrO) or graphene (Or) modified electrode. Significantly, the detection of dopamine is a diffusion-controlled process, highly selective, and has a low detection limit and broad linear range.